This document is published on the edge website as a white paper to help. A refrigeration system where the working fluid changes phase gas, liquid, vaporliquid mixture during the cycle. The search for refrigerants with low global warming potential gwp to replace more harmful hfcs is continuing. Frederick cogswell, united technologies research center. The following table includes the 100year time horizon global warming potentials gwp relative to co2. The effects on the industry of the actions to reduce ozone depletion and global warming are now apparent.
Decision xix6, taken in 2007, to adjust the protocol to accelerate the phase out of. Many fgases have high global warming potential gwp. Ahri project 8006 low global warming potential gwp. The nextgeneration refrigerants will require essentially zero odp and low global warming potential gwp. Ever since the montreal protocol agreed to phase out hydrochlorofluorocarbons hcfcs, there has been an increasing interest within the protocol on climate issues. New low global warming potentialgwp synthetic refrigerants. Ashrae standard 34 2019 lower global warming potential refrigerants. W ith the ratification of the montreal protocol in 1987, chlorofluorocarbon cfc and hydrochlorofluorocarbon hcfc refrigerants, such as r11, r12, r22, and r123, have been or will soon be phased out due to their high ozone depleting potential odp. This table is adapted from the ipcc fifth assessment. Pdf refrigerant types, issues, trends and future options.
Product information sorted by product type and name. Limited options for lowglobalwarmingpotential refrigerants. It mandates that all refrigerants with odp will be phased out for new equipment by january 1, 2020. Global warming impact 15% direct warming impact refrigerant leakage 40% indirect warming impact energy consumption eliminate 45% of global warming impact 2. Hydrofluorocarbons hfcs, which are currently used as refrigerants in airconditioning ac systems, are potent greenhouse gases, with high values of global warming potential gwp. Refrigerant selection to reduce climate impact edge buildings. Global warming potential values the following table includes the 100year time horizon global warming potentials gwp relative to co2.
Global warming potential gwp is a measure of the relative global warming effects of different gases. Guideline for life cycle climate performance august 2015. There are also other potential hfo substances that have been identified that may be used as refrigerants in the future such as hfo1244yd and hfo6mzz. Curbing them is key to climatechange strategy oped. R410a, the most common air conditioning refrigerant in use globally today, is not actually nonflammable. Nextgeneration low global warming potential refrigerants. Odp is expressed as a relative potential of ozone depletion compared to influence of r11 which has odp1. Transitioning to lowgwp alternatives in commercial refrigerations. Ozone is a variant of oxygen, the ozone molecule having three atoms of oxygen. Ozone depletion potential odp of a chemical compound is the relative amount of degradation it can cause to the ozone layer. Refrigerants regulated under the refrigerant management program rmp include any refrigerant that is an ozone depleting substance ods as defined in title 40 of the code of federal regulation, part 82, and any compound with a global warming potential gwp value equal to or greater than 150 according to the gwps specified in ipccs fourth assessment report of 2007. These molecules are hydrofluoroolefins hfo and honeywell has discovered that these molecules have an extremely low global warming potential gwp of only 4 to 6 as compared to 1430 for r.
Refrigerant product information opteon xp40 r449a is a nonozone depleting, low global warming potential gwp, hydrofluoroolefin hfo based refrigerant with an optimal balance of properties to replace r404ar507, r22, or r407 series in positive displacement, direct expansion, low and medium. It is a re lative scale that co mpares a gas to that o f the. Energy and global warming impacts of hfc refrigerants and. Guideline for life cycle climate performance 2015 3. The impact of these new rules will dramatically alter heating and cooling in a wide range of industries over the course of the coming years. Two new low gwp refrigerant molecules hfo1234yf, hfo1234ze have been identified. The impact of the montreal protocol is thus also positive regarding global warming. Simplified index used to estimate the potential influence on global warming caused by the release of a specified gas global warming potential a refrigeration system where the working fluid changes phase gas, liquid, vaporliquid mixture during the cycle. Ashrae position document on refrigerants and their responsible use 2 executive summary refrigerants are the working fluids in refrigeration, airconditioning, and heatpumping systems. Reduce refrigerant leak to 10% per year, refrigerant gwp by 50%, and reduce charge by 65% 40% indirect warming impact energy consumption for large systems, global warming becomes an efficiency. Gfo19301 advancing nextgeneration heating, cooling.
All books are in clear copy here, and all files are secure so dont worry about it. Research and development roadmap for nextgeneration low global warming potential refrigerants introduction 9 1 introduction 1. In addition, costo has agreed to install a glycol secondary loop refrigeration system for all mediumtemperature refrigeration at all onestory stores opened during the next three years. They also have good energy efficiency, but are flammable and can form an explosive mixture with air if a leak occurs. Motor vehicle air conditioning environmental impacts of mvac refrigerants ozone depletion potential global warming potential 1 0 0 0 0 cfc12 hfc4a hfc152a hfo1234yf co. Hfcs are commonly used as refrigerants and propellants in aerosols. Reduce refrigerant gwp by 50% 5% direct warming impact refrigerant leakage eliminate 55% of global warming impact reduce direct impact by 92% 3. Oct 24, 2019 projects will develop systems with efficiencies comparable to or higher than todays high efficiency equipment, while also utilizing low or no global warming potential gwp refrigerants or nonvapor compression nvc technology. Research and development roadmap for nextgeneration low global warming potential refrigerants ii preface preface the u. Global warming potential gwp is a measure of how much heat a greenhouse gas traps in the atmosphere up to a specific time horizon, relative to carbon dioxide. Furthermore, compared to the refrigerants widely used today such as r22 and r410a, r32 has a global warming potential gwp that is onethird lower and is remarkable for its low environmental impact. Global warming potential gwp is a measu re of how much a gi ven mass of greenhous e gas is estimated to contribute to global warming. Linde strongly advocates the use of refrigerant gases with zero ozone depletion potential and fully supports the phase out of hcfcs. An evaluation of the environmental impact of different commercial supermarket refrigeration systems using low global warming potential refrigerants.
Global warming potential data listed in the table are taken from tables 3 and 4 of 20 ashrae handbookfundamentals, chapter 29. Highgwp refrigerants california air resources board. Department of energys doe building technology office bto, a part of the office of energy efficiency and renewable energy, engaged navigant consulting, inc. Secondly, since r744 has no ozone depletion potential and a global warming potential of only one you can be safe in assuming that carbon dioxide will never be phased down our across the world. Low global warming potential refrigerants for commercial. Hfcs have high global warming potentials gwp environmental friendly and safe alternatives in a way the energy efficiency also is improved, are required. Linde can offer alternative refrigerants to r404a, suitable for use in many. Refrigerant types, issues, trends and future options. This site is like a library, you could find million book here by using search box in the header.
Refrigerants containing chlorine or bromine contribute to the breakdown of the ozone layer see figure 5. Frequently asked questions ashrae safety classification of. Identifying refrigerant fluids with low global warming potential by laura ost, national institute of standards and technology. This table is adapted from the ipcc fifth assessment report, 2014 ar5i. In view of the global warming potential of these newly synthesized refrigerants, the recent trend. It also benefits from being mildly flammable according to ashrae class 2l and being nonflammable below 30c. Global warming potential gwp is a measure of how much a given mass of a gas contributes to global. Companies like honeywell are to looking into redesigning appliances like air conditioners and refrigerant applications that have a lower gwp. As concerns about the global warming potential gwp of common fluorocarbon refrigerants have mounted in recent years, lower gwp refrigerants have garnered increasing attention. Dod, gsa, and nasa are issuing a final rule amending the federal acquisition regulation far to implement executive branch policy in the presidents climate action plan to procure, when feasible, alternatives to high global warming potential gwp hydrofluorocarbons hfcs. Study on environmental and health effects of hfo refrigerants.
It compares the amount of heat trapped by a certain mass of the gas in question to the amount of heat trapped by a similar mass of carbon dioxide and is expressed as a factor of carbon dioxide whose gwp is standardized to 1. A growing focus on the environmental impact of refrigerants is fuelling demand for refrigeration solutions that can provide satisfactory cooling performance with a lower global warming impact. Simplified index used to estimate the potential influence on global warming caused by the release of a specified gas. Ozone depletion potential odp of a chemical compound is the relative amount of degradation it can cause to the ozone layerglobal warming potential gwp is a measure of how much a given mass of a gas contributes to global warming. Jul 29, 20 curbing them is key to climatechange strategy oped. It assigns a value to the amount of heat trapped by a certain mass of a gas relative to the amount of heat trapped by a similar mass of carbon dioxide over a specific period of time. The ar5 values are the most recent, but the second assessment report 1995 and fourth. Linde can offer alternative refrigerants to r404a, suitable for use in many applications, that provide substantially lower gwp. Refrigerants can thus also be ranked according to their impact on the stratospheric ozone layer the ozone depletion potential, odp or as greenhouse gases the global warming potential, gwp. This text file should be in a comma separated value format. Highefficiency low globalwarming potential gwp compressor. The targeted system would use low gwp refrigerant, and can provide 30% annual energy savings with potential to save 2.
The global warming potential gwp is the relative measure of the substance impact on the greenhouse effect in relation to the impact of a kilogram of co 2. Ozone depletion and global warming are two major environmental concerns with serious implications for the future development of the refrigerationbased industries. Hfo1234yf and hfo1234ze have low gwp and acceptable potential to replace the common refrigerants like r4a. May 19, 2019 secondly, since r744 has no ozone depletion potential and a global warming potential of only one you can be safe in assuming that carbon dioxide will never be phased down our across the world. Baxter oak ridge national laboratory oak ridge, tennessee sponsored by alternative fluorocarbons environmental acceptability study afeas u. Cfc refrigerants are commonly used in new installations in the united states.
Compared to halogenated refrigerants, hydrocarbons like isobutane r600a and propane r290 offer several advantages. Projects will develop systems with efficiencies comparable to or higher than todays high efficiency equipment, while also utilizing low or no global warming potential gwp refrigerants or nonvapor compression nvc technology. Common refrigerants and their ozone depletion potential odp and global warming potential gwp are indicated below. Gwp is important but not the only measure of environmental impact. They absorb heat from one area, such as an airconditioned space, and reject it into another, such as outdoors, usually through evaporation and condensation. R111, 2 global warming potential 100 year, ipcc 4th assessment report, 2007. This refrigeration playbook provides guidance to refrigeration system design teams about selecting energyefficient refrigeration systems that use lowglobal warming potential gwp refrigerants. Ever since the montreal protocol agreed to phase out hydrochlorofluorocarbons hcfcs, there has been an increasing interest within the protocol on climate. Read online standards for lowglobal warming potential. Global warming potential, or gwp, is a measure of how destructive a climate pollutant is. Honeywells ultralowglobalwarmingpotential refrigerant. In other words, the nist study found no ideal refrigerant that combined low global warming potential gwpa measure of how much heat a gas will trap if released into the atmosphere with other desirable performance and safety features such as being both nonflammable and nontoxic.
It is ashraelisted as an a1 refrigerant, meaning that it has no flame propagation at 63c. Cfcs were also greenhouse gases and their global warming potential was much higher. New refrigerants the tables on page 3 and 4 list the approved refrigerant numbers from the latest edition of standard 34 and addenda that were assigned from 2010 onward. Limited options for lowglobalwarmingpotential refrigerants mark o. The first generation of refrigerants included substances such as hydrocarbons, ammonia, and carbon dioxide. More experiments in different type of cycles and conditions are necessary in. Among the options being evaluated are hydrocarbons like propane, ammonia, carbon dioxide co 2, and newly developed refrigerants like hydrofluoroolefins hfos. Low gwp refrigerants can contribute greatly to greenhouse gas mitigation. Energy and global warming impacts of hfc refrigerants and emerging technologies james r. Low global warming refrigerants for stationary air. Refrigeration and air conditioning have an impact on global warming in three ways. It is a natural refrigerant that has been used for over onehundred years and it will continue to be used for another onehundred years or more.
Use the global warming potential to calculate the carbon dioxide equivalent weight of an f gas. Carbon dioxide has a designated gwp of 1 base reference. Identifying refrigerant fluids with low global warming. By brian fricke, ken schultz, and xudong wang from the february 2017 issue. The uk is phasing down hfcs by 79% by 2030 from the average use between 2009 to 2012. Solstice ze is nonozonedepleting, has a global warming potential of less than 1 and complies with the european fgas regulation which is designed to reduce the global warming impacts of fluorinated refrigerants and other materials. Ashrae position document on refrigerants and their.
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